Volume 11, number 3

Kinetics of Petroleum Sulfides Peroxidation in the Presence of Two Catalysts

Ivan Mikhailovich Borisov1, Zarina Shavketovna Gazizova1, Rima Sergeevn Luksha1 and Gulnaz Rafilevna Shayakhmetova2

1M.Akmullah Bashkir State Pedagogical University, 450000, Russia, Ufa, Oktyabrskoi Revolutsii Street, 3a 2Institute “TatNIPIneft”, 423236, Bugulma, M. Jalil Street, 32

DOI : http://dx.doi.org/http://dx.doi.org/10.13005/bbra/1548

ABSTRACT:

Kinetics was studied and the scheme of the reaction of petroleum sulfides peroxidation to sulfoxides in the presence of catalytic systems «molybdic acid + molybdenum oxide (VI)» and «molybdic acid + wolframic acid» was proposed.

KEYWORDS:

petroleum sulfides; sulfoxides; oxidation; hydrogen peroxide; molybdicand wolframic acids; molybdenum oxide; kinetic models

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